The triphenylphosphine adduct of a copper(I) complex involving an incompletely bound N2S2 macrocyclic ligand

The triphenylphosphine adduct of a copper ( I ) complex involving an incompletely bound N 2 S 2 macrocyclic ligand

Free Energy Calculations of Mutations Involving a Tightly Bound Water Molecule and Ligand Substitutions in a Ligand-Protein Complex.

The accurate calculation of the free energy of interaction of protein-water-ligand systems has an important role in molecular recognition and drug design that is often not fully considered. We report free energy thermodynamic integration calculations used to evaluate the effects of inclusion, neglect, and targeting and removal (i.e., systematic substitution by ligand functional groups) of an im...

Efficient oxidation of sulfides using a molybdenum(VI)–dioxo complex containing an benzimidazole ligand

For the first time, dioxomolybdenum(VI) complex with the general formula [MoO2L2] containing a N-O bidentate ligands (HL=2-(o-aminophenyl)- benzimidazole) has been used for the oxidation of sulfides. Elemental analyses (carbon, hydrogen, nitrogen), FT-IR and Uv-Visble spectra and 1HNMR analysis agree well with the proposed stoicheiometry of the complex [MoO...

Efficient oxidation of sulfides using a molybdenum(VI)–dioxo complex containing an benzimidazole ligand

For the first time, dioxomolybdenum(VI) complex with the general formula [MoO2L2] containing a N-O bidentate ligands (HL=2-(o-aminophenyl)- benzimidazole) has been used for the oxidation of sulfides. Elemental analyses (carbon, hydrogen, nitrogen), FT-IR and Uv-Visble spectra and 1HNMR analysis agree well with the proposed stoicheiometry of the complex [MoO...

Binuclear Complex of Zinc and Copper with Unsymmetrical Macrocyclic Ligand as Sensitizer in Nanocrystaline TiO2 Solar Cells

Dye sensitized solar cells (DSSCs) are considered as one of the most promising alternativerenewable energy sources. In the structure of DSSCs, a photosensitizer composed of transitionmetal complexes is used to harvest light. In this work a binuclear complex containing twopropionitrile pendant arms [ZnLCu(OAC)]PF6 {L = 1, 6- bis (2-cyanoethyl) -2, 5-bis (2-hydroxy3-formyl-5-methylbenzyl)-2, 5- d...